Elements
72

Hf

Hafnium

Pronounced

HAF-ni-em

Hafnium (Hf) is a silvery coloured metal that has the atomic number 72 in the periodic table. It is a Transition metal in Group 4. It has the symbol Hf.

Hafnium was predicted to exist by Mendeleev but it was not until 1911 that Georges Urbain, the discoverer of Lutetium, thought he had discovered Hafnium but it was not to be. It was just a mixture of lanthanides. It was in 1923 that Georg Von Hevesy and Dirk Coster discovered Hafnium by x-ray spectroscopy of Zirconium ores. It is named after the latin ‘Hafnia’ the Latin for the city of Copenhagen. It is used in nuclear control rods to absorb neutrons and is corrosion resistant. Hafnium is not found free in nature but mostly in zirconium ores. It is a solid metal at room temperature with a melting point of 2233°c and a boiling point of 4602°c.

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FAQ's

What is the Melting Point for Hafnium?

Hafnium has a Melting Point of 2227°C, meaning at 2227°C it will turn to a liquid.

What is the Boiling Point for Hafnium?

Hafnium has a Boiling Point of 4603°C, meaning at 4603°C it will turn to a Gas.

What is the Electronegativity of Hafnium?

Hafnium's Electronegativty is 1.3. Electronegativity is a measure of how strongly atoms attract bonding electrons to themselves.

Discovered by

Dirk Coster, Georg von Hevesy

Discovery date

1923

What is the Heat of Vaporization of Hafnium?

Hafnium has a Heat of Vaporization of 575 kJ/mol.

Uses

Used in reactor control rods because of its ability to absorb neutrons.

Sources

Obtained from mineral zircon or baddeleyite.

About the author

Nathan M

Author

Nathan has a degree in BSc Biomedical Chemistry at Warwick University and a degree in PGCE Science at Wolverhampton University, UK. Nathan's subject matter ranges from general chemistry and organic chemistry. Nathan also created the curriculum on Breaking Atom in the course page.

Citation

"Hafnium" Published on Dec 30, 2019. https://breakingatom.com/elements/hafnium
72
Protons
72
Electrons
106
Neutrons

Hf

Element Symbol
Hf
Atomic Weight
178.49
Atomic Number
72
State
Solid
Melting Point
Unknown
2227
°C
Boiling Point
4603
Unknown
°C
Heat of Vaporization
575
Unknown
kJ/mol
Crystal Structure
Hexagonal
Thermoconductivity
0.23
Unknown
W/cmK
Shells
2,8,18,32,10,2
Group
Transition Metal
Period
6
Block
D Block
Orbitals
[Xe] 4f14 5d2 6s2
Coefficient of Thermal Expansion
5.9 10^-6 K^-1
Covalent Radius
1.44 Å
Density at 293K
13.2 g/cm³
Electrical Conductivity
0.0312 10^6/cm ohm
First Ionization Potential
6.8251 V
Second Ionization Potential
14.925 V
Third Ionization Potential
23.32 V
Ionic Radius
.83 (+4) Å
Oxydation States
4
Lattice Parameter
3.1947 Å
Lattice Parameter 2
--
Lattice Parameter 3
4.458 Å
Orbital configuration
2,8,18,32,10,2

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Explore Other Transition Metals

Transition metal is any of various chemical elements that have valence electrons (electrons that can participate in the formation of chemical bond) in two shells instead of only one. They form group 3 (IIIb) through group 12 (IIb).
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